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• W2952472699 abstract "An indole-templated ring-closing metathesis has been used to create the central nine-membered ring of the cleavamine-type alkaloids. A subsequent intramolecular vinyl halide Heck reaction upon the resulting azacyclononene ring completes the assembly of the strained 1-azabicyclo[6.3.1]dodecane framework of the alkaloids. The usefulness of the approach is illustrated with the synthesis of (±)-cleavamine and (±)-dihydrocleavamine." @default.
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• W2952472699 date "2011-03-10" @default.
• W2952472699 modified "2023-10-18" @default.
• W2952472699 title "A Straightforward Synthetic Entry to Cleavamine-Type Indole Alkaloids by a Ring-Closing Metathesis−Vinyl Halide Heck Cyclization Strategy" @default.
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• W2952472699 doi "https://doi.org/10.1021/ol200437k" @default.
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