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- W2952474516 abstract "The crystal and molecular structure of the title compound has been determined from diffractometer data (840 reflections) and refined by full-matrix least-squares to R 0·047. Crystals are orthorhombic, space group P212121, a= 14·786(2), b= 10·137(1), c= 9·440(1)A, Z= 4.The chromium atom is octahedrally co-ordinated by the organic ligand which is bidentate through the olefinic bond and one of the methoxy-groups [Cr–C 2·248 and 2·300(8), Cr–O 2·152(5)A] and by the four carbonyl groups. Among the latter, an interesting comparison is found between the opposed pair of carbonyl groups with Cr–C 1·915 ± 0·015 and C–O 1·125 ± 0·015 A and the pair opposite the ligand with Cr–C 1·83 ± 0·015 and C–O 1·165 ± 0·015 A." @default.
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- W2952474516 date "1974-12-17" @default.
- W2952474516 modified "2023-09-24" @default.
- W2952474516 title "ChemInform Abstract: CRYSTAL AND MOLECULAR STRUCTURE OF TETRACARBONYL-(7,7-DIMETHOXYNORBORN-2-ENE)CHROMIUM(0)" @default.
- W2952474516 cites W2037147660 @default.
- W2952474516 doi "https://doi.org/10.1002/chin.197450389" @default.
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