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- W2952481578 abstract "A novel strategy involving Cu-catalyzed oxidative transformation of ketone-derived hydrazone moiety to various synthetic valuable internal alkynes and diynes has been developed. This method features inexpensive metal catalyst, green oxidant, good functional group tolerance, high regioselectivity and readily available starting materials. Oxidative deprotonation reactions were carried out to form internal alkynes and symmetrical diynes. Cross-coupling reactions of hydrazones with halides and terminal alkynes were performed to afford functionalized alkynes and unsymmetrical conjugated diynes. A mechanism proceeding through a Cu-carbene intermediate is proposed for the CC triple bond formation." @default.
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- W2952481578 date "2015-04-23" @default.
- W2952481578 modified "2023-09-27" @default.
- W2952481578 title "ChemInform Abstract: Copper-Catalyzed Aerobic Oxidative Transformation of Ketone-Derived N-Tosyl Hydrazones: An Entry to Alkynes." @default.
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- W2952481578 doi "https://doi.org/10.1002/chin.201519088" @default.
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