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- W2952484906 abstract "Aesthetically pleasing, interlocked ring systems (catenanes) accumulate charge, as they are prepared from neutral ligands and cations. A new approach to the fabrication of charge neutral catenanes, based on designed dianionic ligands and divalent cations is presented. Ba2L2(H2L = 3,5,25,27-tetraoxo-6,7,12,15,18,21,24-heptaoxanonaeisane) represents a new member of the class of helical metal containing catenanes. Each ligand in Ba2L2 acts as a double-stranded heterotopic catenand. The two helicates are interlocked to form a [2] catenane. Ba2L2 is a rare example of a heterotopic, homodinuclear catenane. Most heterotopic catenates hold two different metal centers, the binding environments being tailored for each metal; e.g., a metal with preference for 4-coordination binding two bipyridyls and one with preference for 6-coordination binding two terpyridyls. The coordinative flexibility of Ba2+ permits coordination both to the pseudo-crown ether portion of the catenand, as well as to the anionic ketoester moiet..." @default.
- W2952484906 created "2019-06-27" @default.
- W2952484906 creator A5016756510 @default.
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- W2952484906 date "2010-05-23" @default.
- W2952484906 modified "2023-09-24" @default.
- W2952484906 title "ChemInform Abstract: Ligand Design for Stabilization of Group 2 Element Compounds by Intramolecular Coordination" @default.
- W2952484906 cites W2106352530 @default.
- W2952484906 doi "https://doi.org/10.1002/chin.200203257" @default.
- W2952484906 hasPublicationYear "2010" @default.
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