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- W2952490117 abstract "Sodium indium(III) chromate(VI) dihydrate, NaIn(CrO4)2·2H2O, synthesized from an aqueous solution at room temperature, is the first indium(III) member of the large family of compounds with kröhnkite [Na2CuII(SVIO4)2·2H2O]-type chains. The crystal structure is based on infinite octahedral–tetrahedral [In(CrO4)2(H2O)2]− chains along [010], linked via charge-balancing Na+ cations. The slightly distorted InO4(H2O)2 octahedra are characterized by a mean In—O distance of 2.125 Å. The CrO4 tetrahedra are strongly distorted (mean Cr—O = 1.641 Å). The Na atom shows an octahedral coordination, unprecedented among compounds with kröhnkite-type chains. The NaO6 octahedra share opposite edges with the InO4(H2O)2 octahedra to form infinite [001] chains. The hydrogen bonds are of medium strength. NaIn(CrO4)2·2H2O belongs to the structural type F2 in the classification of Fleck, Kolitsch & Hertweck [Z. Kristallogr. (2002), 217, 435–443], and is isotypic with KAl(CrO4)2·2H2O and MFe(CrO4)2·2H2O (M = K, Tl or NH4). All atoms are in special positions except one O atom." @default.
- W2952490117 created "2019-06-27" @default.
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- W2952490117 date "2006-04-29" @default.
- W2952490117 modified "2023-09-24" @default.
- W2952490117 title "NaIn(CrO<sub>4</sub>)<sub>2</sub>·2H<sub>2</sub>O, the first indium(III) member of the kröhnkite family" @default.
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- W2952490117 doi "https://doi.org/10.1107/s0108270106012996" @default.
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