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- W2952502444 abstract "Mild conditions (1.2 eq. Hg(OAc)2, 1.2 eq. TBAF in 1:1 MeOH/THF; 35 min at 0 °C) have been developed for the protodesilylation of α-dimethylphenylsilyl esters. An enolate-dependent mechanism for the reaction was supported through studies indicating the clean incorporation of deuterium. To further investigate the mechanism, the optimal conditions as well as the kinetics of the reaction were explored." @default.
- W2952502444 created "2019-06-27" @default.
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- W2952502444 date "2010-06-16" @default.
- W2952502444 modified "2023-09-24" @default.
- W2952502444 title "ChemInform Abstract: A Mild Method for Protodesilylation of α-Dimethylphenylsilyl Ester Substrates." @default.
- W2952502444 cites W1998948846 @default.
- W2952502444 doi "https://doi.org/10.1002/chin.199914039" @default.
- W2952502444 hasPublicationYear "2010" @default.
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