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- W2952502690 abstract "A comparative study using cyclic, differential pulse, and Osteryoung square wave voltammetry is presented on organofullerenes derivatized with oxygen-, carbon-, and silicon-containing groups. Electron affinities of the organofullerenes increase with increasing electronegativities of the attached atoms. C[sub 60]O is a stronger electron acceptor than C[sub 60], although its electroreductions are CV irreversible. In the carbon-derivatized C[sub 60], hybridization of the attached carbon atoms and electron-withdrawing groups also affect their reduction potentials. As previously described for C[sub 60], no CV reversible electrooxidation waves were observed for all organofullerenes studied. Electron-donating groups, such as alkyl and silyl, significantly lower the oxidation potentials of the organofullerenes. The AM1 molecular orbital calculations were performed on C[sub 60] and selected organofullerenes. The first and second reduction potentials correlate well with the LUMO energy levels, while the third reduction potentials correlate better with the LUMO+1 energy levels. The peak oxidation potentials also show a good linear correlation with the HOMO energy levels. 23 refs., 5 figs., 1 tab." @default.
- W2952502690 created "2019-06-27" @default.
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- W2952502690 date "2010-08-19" @default.
- W2952502690 modified "2023-09-26" @default.
- W2952502690 title "ChemInform Abstract: Redox Properties of Organofullerenes." @default.
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- W2952502690 doi "https://doi.org/10.1002/chin.199426118" @default.
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