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- W2952502766 abstract "Catalytic addition of chiral phosphine, that is, (R)- or (S)-SITCP, to an α-substituted allene ester generated a zwitterionic dipole. Under optimized reaction conditions, this dipole could engage isatine-derived N-Boc-ketimines in a novel mode of [3+2] annulation reaction. Pyrrolinyl spirooxindoles are thus afforded in high yields and with excellent enantioselectivities. The unprecedented annulation reaction successfully facilitated the construction of sp(3) -rich and highly substituted 3,2'-pyrrolidinyl spirooxindoles supporting many chiral centers." @default.
- W2952502766 created "2019-06-27" @default.
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- W2952502766 date "2016-11-01" @default.
- W2952502766 modified "2023-09-23" @default.
- W2952502766 title "ChemInform Abstract: Engaging Allene-Derived Zwitterions in an Unprecedented Mode of Asymmetric [3 + 2]-Annulation Reaction." @default.
- W2952502766 cites W2461347989 @default.
- W2952502766 doi "https://doi.org/10.1002/chin.201650081" @default.
- W2952502766 hasPublicationYear "2016" @default.
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