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- W2952510163 abstract "Abstract UW4C4 crystallizes tetragonally, space group P4/m, a = 832.71(9) pm, c = 313.58(9) pm, with Z = 2 formula units per cell. The structure was determined from single-crystal X-ray data and refined to a residual of R = 0.046 for 436 structure factors and 24 variable parameters. It is closely related to that of tetragonal UCr4C4, from which it can be derived by small distortions which lower the symmetry from I4/m to P4/m. This results in two different (distorted octahedral) carbon environments: one where the (four) C-W distances are relatively long and the (two) C-U distances are short and one where the opposite is the case. In addition there are significant differences in the metal-metal bonding of UCr4C4 and UW4C4. Both carbides are paramagnetic at room temperature with slightly increasing susceptibilities at lower temperatures as is frequently observed for uranium-containing intermetallics. The two compounds UWC2 and U2W2C3 are confirmed and the phase equilibria of the ternary U-W-C system are reported." @default.
- W2952510163 created "2019-06-27" @default.
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- W2952510163 date "1990-07-03" @default.
- W2952510163 modified "2023-09-24" @default.
- W2952510163 title "ChemInform Abstract: UW4C4, a Distorted Structure Derived from UCr4C4 and the Ternary U-W-C System." @default.
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- W2952510163 doi "https://doi.org/10.1002/chin.199027003" @default.
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