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- W2952518570 abstract "Abstract 1,4-Disilylation of β,β-unsaturated ketones with 1,1-dichloro-l-phenyl-2,2,2-trimethyldisilane proceeded in the presence of phosphine-palladium catalysts in benzene. High enantio-selectivity (up to 92%) was observed in the disilylation with dichloro[( R )-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]palladium(II) as a catalyst (0.5 mol %). The disilylation products, 1-(trimethyisilyloxy)-3-(dichlorophenylsilyl)propenes, were readily converted into optically active α-unsubstituted or anti α-substituted β-(phenyldimethylsilyl) ketones, the oxidation of which gave the corresponding optically active β-hydroxy ketones in high yields." @default.
- W2952518570 created "2019-06-27" @default.
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- W2952518570 date "2010-08-19" @default.
- W2952518570 modified "2023-09-25" @default.
- W2952518570 title "ChemInform Abstract: Catalytic Asymmetric Synthesis of β-Hydroxy Ketones by Palladium- Catalyzed Asymmetric 1,4-Disilylation of α,β-Unsaturated Ketones." @default.
- W2952518570 cites W1969239789 @default.
- W2952518570 doi "https://doi.org/10.1002/chin.199419076" @default.
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