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• W2952522982 endingPage "6364" @default.
• W2952522982 startingPage "6351" @default.
• W2952522982 abstract "The 1,3-dipolar cycloadditions between imidate 1, derived from dimethylaminomalonate and aldehydes 2(a-f), phthalaldehyde 2g, isophthalaldehyde 2h. 4-chlorophenylisocyanate 9a, ethoxycarbonylisothiocyanate 9d as dipolarophiles proceeds regioselectively in good yield using solvent-free conditions. Synthesis of ortho- and meta-bis-(2′-oxazoline-5′-yl)benzenes 6g, 6h are also reported. The regiochemistry and the reactivity in these cycloaddition reactions are rationalized by PM3 MO calculations. The stereoselective demethoxycarbonylation of dimethyl 2-oxazoline-4,4-dicarboxylate 4a is described. The mild hydrolysis of 5-(2-formylphenyl)-2-oxazoline 4g leads to the formation of a new 3,4-dihydroisoquinoline 8h in quantitative yield." @default.
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• W2952522982 date "1997-05-01" @default.
• W2952522982 modified "2023-10-16" @default.
• W2952522982 title "A new route to 2-oxazolines, bis-oxazolines, and 2-imidazoline-5-ones from imidates using solvent-free cycloadditions: Synthesis, chemical properties, and PM3 MO calculations" @default.
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• W2952522982 doi "https://doi.org/10.1016/s0040-4020(97)00295-0" @default.
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