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- W2952545428 abstract "The mechanical strength of most glasses and ceramics decreases with time under static loading in an ambient environment. This strength loss is associated with slow growth of preexisting surface flaws due to stress corrosion by water from the surrounding environment. We studied stress corrosion in vitreous silica exposed to water and several nonaqueous environments; environments which enhance stress-corrosion crack growth in silica contain active groups with electron donor sites on one end and proton donor sites at the other. These results suggest a detailed chemical model for the interaction of the environment with mechanically strained bonds in the solid at the tip of a crack. The proposed model for stress-corrosion crack growth also has implications for the long-term strength behavior of a wide variety of brittle materials." @default.
- W2952545428 created "2019-06-27" @default.
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- W2952545428 date "1983-07-12" @default.
- W2952545428 modified "2023-09-26" @default.
- W2952545428 title "ChemInform Abstract: A MOLECULAR MECHANISM FOR STRESS CORROSION IN VITREOUS SILICA" @default.
- W2952545428 cites W2131300332 @default.
- W2952545428 doi "https://doi.org/10.1002/chin.198328024" @default.
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