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- W2952554908 abstract "Aqueous sodium hypochlorite in acetonitrile gave, respectively, 1-trifluoromethylnonafluoro-1,2-epoxycyclohexane (2) from 1-trifluoromethylnonafluorocyclohex-1-ene, and the bis-(1, 2):(4, 5)-epoxide from 1-trifluoromethylheptafluorocyclohexa-1,4-diene. From epoxide (2) and lithium aluminium hydride, 1H2H-2-trifluoromethyloctafluorocyclohexanol was formed, and (2) with potassium fluoride afforded potassium 2-trifluoromethyldecafluorocyclohexanolate (6). The two stereoisomers of 1-methoxy-2-trifluoromethyldecafluorocyclohexane were obtained from alkoxide (6) and dimethyl sulphate: warming of (6) gave 2-trifluoromethylnonafluorocyclohexanone (9). Epoxide (2) with sodium methoxide afforded two acyclic products, methyl decafluoro-6-methoxyhept-5-enoate (10) and methyl nonafluoro-5, 6-dimethoxyhept-5-enoats, via a sequence which included a ring-opening haloform cleavage stage. Reaction of ketone (9) with sodium methoxide also gave two acyclic esters, (10) and its positional isomer, methyl decafluoro-6-methoxyhept-4-enoate, as an inseparable mixture. Again, ring-opening was by a heloform cleavage." @default.
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- W2952554908 date "1990-07-01" @default.
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- W2952554908 title "Polyfluoro-1,2-epoxy-alkanes and -cycloalkanes. Part VI. The synthesis and some reactions of 1-trifluoromethylnonafluoro-1,2-epoxycyclohexane" @default.
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- W2952554908 doi "https://doi.org/10.1016/s0022-1139(00)80360-7" @default.
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