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- W2952573209 abstract "The applicability of 2-bromo-4,6-dimethoxy-3(2H)-benzofuranone (1) to produce flavonoid-derived epoxides in the course of the Darzens reaction with aldehydes was investigated. However, instead of the epoxides, flavonols 3 and, in certain cases, benzofuranyl-substituted flavonols 4 were isolated. The generation of 3 is assumed due to a ring expansion of the initially formed epoxides. These flavonols can react with 1 to produce the unexpected 1:2 adducts 4 as minor products. The structure of the hexamethoxy derivative 4b (R1 = H, R2 = R3 = OMe) was confirmed by X-ray crystallographic analysis." @default.
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- W2952573209 date "2008-07-01" @default.
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- W2952573209 title "Darzens reaction of 2-bromo-4,6-dimethoxy-3(2H)-benzofuranone with aromatic aldehydes to form flavonoids" @default.
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- W2952573209 doi "https://doi.org/10.1002/jhet.5570450432" @default.
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