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- W2952593583 abstract "2-(Trimethylsilylmethyl) cyclopropyl ketones were smoothly cleaved with boron trifluorideacetic acid complex under mild reaction conditions with the assistance of the trimethylsilyl group to give γ, δ-enones in good yields. The major effect of the trimethylsilyl group in the ring opening of the cyclopropyl ketones was unambiguously confirmed in the dicyclopropyl ketone 15 : one of its two cyclopropyl rings, which has a trimethylsilylmethyl group, was selectively cleaved. Furthermore, the reaction was applied to the formal total synthesis of cis-jasmone." @default.
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- W2952593583 date "1984-05-15" @default.
- W2952593583 modified "2023-09-27" @default.
- W2952593583 title "ChemInform Abstract: SILICON-ASSISTED RING OPENING OF CYCLOPROPYL KETONES WITH BORON TRIFLUORIDE-ACETIC ACID COMPLEX" @default.
- W2952593583 cites W2322683400 @default.
- W2952593583 doi "https://doi.org/10.1002/chin.198420180" @default.
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