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- W2952596927 abstract "A route for the synthesis of enantiopure allene-substituted lactams has been developed. The key-step involves the copper(I) mediated SN2′ substitution of propargylic tosylates by a (S)-pyroglutamic acid derived organozinc reagent. Pd-catalysed reaction of these allenes with iodobenzene afforded enantiopure bicyclic enamides. Furthermore the unexpected formation of an interesting diene is reported." @default.
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- W2952596927 date "1998-10-01" @default.
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- W2952596927 title "Palladium-Catalysed Cyclisation of Enantiopure Allenic Lactams Prepared from a Pyroglutamic Acid Derived Organozinc Reagent" @default.
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- W2952596927 doi "https://doi.org/10.1055/s-1998-1859" @default.
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