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- W2952597644 abstract "Axially dissymmetric bisphosphine ligands, (R)- and (S)-2,2′-bis(diphenylphosphinoamino)-1,1′-binaphthyl (BDPAB) and (R)-2,2′-bis[N-(diphenylphosphino)methylamino]-1,1′-binaphthyl (Me-BDPAB) were conveniently prepared from 2,2′-diamino-1,1′-binaphthyl. The rhodium(I)-catalyzed asymmetric hydrogenation of α-acylamidoacrylic acids and esters gave the corresponding amino acids of up to 95% optical purity. The sign of the centro-chirality of the product amino acids was always the same to that of the axial chirality of the ligand in both cases of BDPAB and Me-BDPAB." @default.
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- W2952597644 date "1984-12-11" @default.
- W2952597644 modified "2023-09-27" @default.
- W2952597644 title "ChemInform Abstract: AXIALLY DISSYMMETRIC BIS(AMINOPHOSPHINE)S DERIVED FROM 2,2′-DIAMINO-1,1′-BINAPHTHYL. SYNTHESIS AND APPLICATION TO RHODIUM(I)-CATALYZED ASYMMETRIC HYDROGENATIONS" @default.
- W2952597644 cites W1985709614 @default.
- W2952597644 doi "https://doi.org/10.1002/chin.198450282" @default.
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