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- W2952606980 abstract "Here, a palladium-catalyzed functionalization of unactivated sp3 C–H bonds with internal alcohol nucleophiles is described. Directed by an oxime-masked alcohol, annulation chemoselectively occurs at the β position, leading to a range of aliphatic cyclic ethers with four- to seven-membered rings. Tethered primary, secondary, and tertiary free hydroxyl groups can all react to give the corresponding cyclized products. In addition, benzyl and silyl protected alcohols can also be directly coupled. An sp3 C–H activation/intramolecular SN2 pathway was proposed." @default.
- W2952606980 created "2019-06-27" @default.
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- W2952606980 date "2016-02-01" @default.
- W2952606980 modified "2023-09-27" @default.
- W2952606980 title "ChemInform Abstract: Cyclic Ether Synthesis via Palladium-Catalyzed Directed Dehydrogenative Annulation at Unactivated Terminal Positions." @default.
- W2952606980 cites W1261770014 @default.
- W2952606980 doi "https://doi.org/10.1002/chin.201609130" @default.
- W2952606980 hasPublicationYear "2016" @default.
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