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• W2952607592 abstract "A novel, concise and efficient synthesis of substituted isocoumarins is disclosed. o-Allylbenzaldehydes prepared from isovanillin were mediated by PdCl(2)-CuCl(2) in water to undergo a domino reaction sequence, including 6-exo-trig cyclization, the addition of water, the elimination of PdHCl, the isomerization of carbon-carbon double bond, the oxidation of hemiacetals with the elimination of PdHCl, and regeneration of PdCl(2)in situ to yield a series of new substituted isocoumarins in high yields, in one pot." @default.
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• W2952607592 date "2012-08-30" @default.
• W2952607592 modified "2023-10-08" @default.
• W2952607592 title "Pd(II)-Mediated Cyclization of <i>o</i>-Allylbenzaldehydes in Water: A Novel Synthesis of Isocoumarins" @default.
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• W2952607592 doi "https://doi.org/10.1021/ol302256y" @default.
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