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- W2952609713 abstract "The three apocarotenoids methyl (9Z)-8′-oxo-6,8′-diapocaroten-6-oate (2), methyl (9Z)-10′-oxo-6,10′-diapocaroten-6-oate (4), and methyl (9Z)-14′-oxo-6,14′-diapocaroten-6-oate (5), recently isolated from annatto, were synthesized. The key step of all three syntheses was the Wittig reaction of the (Z)-terminus 6 with the phosphonium salts 15, 18, and 24, carrying the polyene chain. Bixin (1) was synthesized from 2 in a Horner-Emmons reaction." @default.
- W2952609713 created "2019-06-27" @default.
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- W2952609713 date "1999-05-05" @default.
- W2952609713 modified "2023-10-18" @default.
- W2952609713 title "Synthesis of Bixin and Three Minor Carotenoids from Annatto (Bixa orellana)" @default.
- W2952609713 doi "https://doi.org/10.1002/(sici)1522-2675(19990505)82:5<696::aid-hlca696>3.0.co;2-x" @default.
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