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- W2952619975 abstract "Abstract The structural and textural properties of a Sn-0.4BPO 4 composite material synthesized by ex situ dispersion of β-Sn in a BPO 4 matrix were investigated by using several complementary techniques to study the global order (XRD, TGA-DSC, SEM-XEDS) and the local order (FT-IR, 119 Sn Mossbauer spectroscopy and X-ray absorption spectroscopy). The results reveal that the composite material consists of three main components: an electrochemically active species “Sn”, an inactive matrix “BPO 4 ”, and an amorphous Sn(II) borophosphate which acts as a link between the two former and which improves the cohesion of the composite. The electrochemical performances of the composite material were tested in Swagelok-type cells with metallic Li as counter-electrode. It shows a high reversible capacity of about 500 mAh g −1 at a C/20 rate, and a very good stability under cycling even at very fast rates of C or C/1.3." @default.
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- W2952619975 date "2010-01-01" @default.
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- W2952619975 title "Sn-0.4BPO4 composite as a promising negative electrode for rechargeable lithium batteries" @default.
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- W2952619975 doi "https://doi.org/10.1016/j.solidstatesciences.2009.10.004" @default.
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