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- W2952636322 abstract "The reduction of the tetrachloroaurate (III) anion by L (L = PPh3, AsPh3, SbPh3) is quantitative in non-aqueous solution. The products are the gold(I)-complexes AuClL (L = AsPh3, SbPh3) and Au(PPh3)+2 together with the corresponding oxidation product LCl2. Kinetic studies show that the reactions are first order in AuCl−1 and L. In addition a path independent of PPh3 was found in dichloromethane. These data are interpreted in terms of mechanisms which involve reduction of AuCl−4 to AuCl−2 followed by equilibrium formation of AuClL for L = AsPh3 and SbPh3. For PPh3, the data are consistent with a chloride replacement by PPh3 to give AuCl3 PPh3, which is followed by a rapid reduction by a second mole of PPh3. Equilibrium formation constants are reported for several Au(I) complexes." @default.
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- W2952636322 date "1974-02-05" @default.
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- W2952636322 title "ChemInform Abstract: OXIDATION - REDUCTION REACTIONS OF TETRACHLOROAURATE(III) ANION WITH TRIPHENYL DERIVATIVES OF GROUP V ELEMENTS" @default.
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- W2952636322 doi "https://doi.org/10.1002/chin.197405347" @default.
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