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- W2952655105 abstract "The cyclopropane ring of 4α,14α,(24ξ)-24-trimethyl-9β19-cyclo-5α-cholestane-3β-ol is opened by microsomes isolated from maize embryos to yield 4α,14α,(24ξ)-24-trimethyl-5α-cholest-8-en-3β-ol. In contrast, when 4β,14α,(24ξ)-24-trimethyl-9β, 19-cyclo-5α-cholestane-3β-ol or 4,4,14α(24ξ)-24-tetramethyl-9β, 19-cyclo-5α-cholestane-3β-ol are used as substrates, no reaction takes place. These results show that the number and also the stereochemistry of the C-4-methyls control the enzymic reaction. A new synthetic method for preparing 4β-methyl from 4α-methyl sterols is also described." @default.
- W2952655105 created "2019-06-27" @default.
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- W2952655105 date "1979-06-05" @default.
- W2952655105 modified "2023-10-14" @default.
- W2952655105 title "ChemInform Abstract: EFFECT OF THE CONFIGURATION OF THE METHYL GROUP AT C-4 ON THE CAPACITY OF 4-METHYL-9β, 19-CYCLOSTEROIDS TO BE SUBSTRATES OF A CYCLOPROPANE CLEAVAGE ENZYME FROM MAIZE" @default.
- W2952655105 cites W2065097778 @default.
- W2952655105 doi "https://doi.org/10.1002/chin.197923313" @default.
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