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- W2952686918 abstract "Diastereoselective trans-olefinations of carboxylic esters 3a−h have been accomplished using benzylic or allylic benzotriazole derivatives 1a−e to prepare α-(benzotriazol-1-yl) ketones 4a−i, for the subsequent reduction of 4a−i, and finally for low-valent titanium-effected dehydroxybenzotriazolylation.1 N-Protected α-amino acid esters 9a−c and 15 thus give allylamines 13a−e and 19 with virtually full retention of chirality. Mechanistic aspects of the dehydroxybenzotriazolylation are discussed." @default.
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- W2952686918 date "1998-04-28" @default.
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- W2952686918 title "Benzotriazole-Mediated Stereoselective Olefination of Carboxylic Esters: Transformation of α-Amino Acid Esters into Chiral Allylamines" @default.
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