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- W2952688676 abstract "A one-pot copper(II)-catalyzed tandem synthesis of 2-substituted pyrrolo[1,2-b]pyridazin-4(1H)-ones from N-aminopyrroles was developed. This tandem reaction involves a Conrad–Limpach-type reaction, including the thermal condensation of N-aminopyrroles with the carbonyl group of β-oxo esters followed by the cyclization of Schiff base intermediates. Compared to the traditional Conrad–Limpach quinoline synthesis, we herein successfully applied copper(II) as a catalyst in this transformation to furnish 2-substituted pyrrolo[1,2-b]pyridazin-4(1H)-ones for the first time. Most of the substrates bearing electron-donating (EDG) and electron-withdrawing (EWG) groups worked well with this procedure. The corresponding products could be converted directly into diverse pyrrolo[1,2-b]pyridazine for drug discovery and materials science." @default.
- W2952688676 created "2019-06-27" @default.
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- W2952688676 date "2015-10-15" @default.
- W2952688676 modified "2023-09-23" @default.
- W2952688676 title "ChemInform Abstract: A One-Pot Copper(II)-Catalyzed Tandem Synthesis of 2-Substituted Pyrrolo[1,2-b]pyridazin-4(1H)-ones." @default.
- W2952688676 cites W1768976006 @default.
- W2952688676 doi "https://doi.org/10.1002/chin.201544184" @default.
- W2952688676 hasPublicationYear "2015" @default.
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