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• W2952693274 abstract "Several 1,2-diphenyl-3-alkynylcyclopropenes were prepared by the reaction of acetylenic nucleophiles with diphenylcyclopropenylium perchlorate. The cyclopropenes were converted into alkynylcyclopropenylium salts via hydride abstraction with triphenylmethyl cation. Attempts to prepare a dication from either ethyne-bridged or butadiyne-bridged biscyclopropenes produced only the corresponding monocations. A dication was prepared when an ethylene spacer was inserted between the acetylene groups of the butadiyne-bridged biscyclopropene. Single-crystal X-ray structures of three of the cyclopropenylium ions were obtained. pK(R+) titrations were carried out on two of the salts, which showed that acetylene substituents provide about the same degree of stability to the cyclopropenylium core as a phenyl group. Nucleophilic addition to the alkynylcyclopropenylium ions under kinetic conditions gave a statistical mixture of products; however, under thermodynamic reaction conditions, nucleophilic addition followed by ring opening produced only one of three possible products. Calculations at the ab initio level were carried out to determine the charge distribution of the cations." @default.
• W2952693274 created "2019-06-27" @default.
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• W2952693274 date "2000-02-11" @default.
• W2952693274 modified "2023-10-14" @default.
• W2952693274 title "Preparation, X-ray Crystal Structures, and Reactivity of Alkynylcyclopropenylium Salts" @default.
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• W2952693274 doi "https://doi.org/10.1021/jo9915372" @default.
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