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- W2952708840 abstract "Modern organic synthesis predominately relies on functional group reactivity differences to achieve the chemoselective formation of desired products. Herein we report a one-pot multistep asymmetric catalytic reaction in which substrates with similar chemical reactivities are differentiated on the basis of polarity. The one-pot reaction involves two catalysts and three substrates in the presence of water. The reaction mixture consists of two phases: a polar aqueous phase and a hydrophobic organic phase. The biphasic nature of the reaction medium and the polarity properties of the substrates and catalysts enable the selective formation of a major product instead of a statistical mixture of four possible products. We chose a two-step reaction involving condensation and subsequent conjugate addition as a model to develop a polarity-directed cascade reaction. Both reaction steps can involve linear aliphatic aldehydes as substrates (Scheme 1). Our aim was to combine the two reaction" @default.
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- W2952708840 date "2010-07-09" @default.
- W2952708840 modified "2023-10-15" @default.
- W2952708840 title "ChemInform Abstract: Polarity-Directed One-Pot Asymmetric Cascade Reactions Mediated by Two Catalysts in an Aqueous Buffer." @default.
- W2952708840 cites W2137235844 @default.
- W2952708840 doi "https://doi.org/10.1002/chin.201031058" @default.
- W2952708840 hasPublicationYear "2010" @default.
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