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- W2952728434 abstract "as-Pt(NH)2(HO) with N-acetylglycine (acglyH) gives initially cis-Pt(NH)(acglyH-G)(H2O), which then undergoes chelate ring closure to Pt(NH)(acglyH-N,O). Deprotonation results in precipitation of Pt(NH)2(acgly-N,O)*2HO. These compounds represent the first reported complexes in which acetylglycine acts as an N,O-chelating ligand. Acid dissociation constants for the deprotonation have been determined by NMR in H0 (2.6 ± 0.1) and D0 (3.4 ± 0.3). In strongly alkaline solution, m-Pt(NH)(acgly-N)(OH)” is formed, while, in strongly acidic solution, the acetylglycine ligand is completely dissociated. Solutions near pH 2, which were exposed to light, slowly developed blue colors." @default.
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- W2952728434 date "1989-06-13" @default.
- W2952728434 modified "2023-09-28" @default.
- W2952728434 title "ChemInform Abstract: Reaction of the cis-Diamminediaquaplatinum(II) Cation with N-Acetylglycine." @default.
- W2952728434 cites W2022700413 @default.
- W2952728434 doi "https://doi.org/10.1002/chin.198924259" @default.
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