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- W2952729023 abstract "Anions of heteroaromatic 1,3-dicarbonyl compounds, such as 4-hydoxy-2-quinolones and 4-hydroxy-coumarins, react in DMF in the presence of potassium carbonate with diaryl disulfides to yield 3-arylsulfenyl derivatives. The arylthiolate anions formed in this reaction can be oxidized by air to yield the starting diaryl disulfides again. Tetraalkylthiuram disulfides react in the same manner to yield 3-dialkylaminothiocarbonylthio derivatives of the title compounds. Oxidation of the arylthioderivatives with hydrogen peroxide in sodium hydroxide solution usually leads to sulfoxides, whereas oxidation with peracetic acid affords sulfones." @default.
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- W2952729023 date "2010-06-12" @default.
- W2952729023 modified "2023-09-26" @default.
- W2952729023 title "ChemInform Abstract: Sulfenylation of Heterocyclic 1,3-Dicarbonyl Compounds." @default.
- W2952729023 cites W8303470 @default.
- W2952729023 doi "https://doi.org/10.1002/chin.199950060" @default.
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