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- W2952732425 abstract "The hydrogenation of cyclopentadiene on Ni catalyst was carried out with a fixed bed reactor.The initial reaction rates were expressed by the following equations. The activation energies of overall-and surface-reaction rates were, respectively, 1.9 and 6.5 kcal/mol and the heats of adsorption of hydrogen and cyclopentadiene were, respectively, 5.6 and 1.6 kcal/mol.The hydrogenation of cyclopentadiene on Ni catalyst is a consecutive reaction passing through cyclopentene, where the activation energy of the 1st stage is higher than that of the 2nd one, namely, E1 > E2. At the lower ratio of PH/PC, cyclopentene is produced with 100% selectivity, whereas, increasing PH/PC or W/F0, the selectivity decreases. At the intermediate reaction temperature, there appears the minimum selectivity. This phenomenon is considered to be due to E1 > E2." @default.
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- W2952732425 date "1975-04-01" @default.
- W2952732425 modified "2023-09-23" @default.
- W2952732425 title "ChemInform Abstract: HYDROGENATION OF CYCLOPENTADIENE ON A NICKEL CATALYST" @default.
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- W2952732425 doi "https://doi.org/10.1002/chin.197513202" @default.
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