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- W2952746250 abstract "The synthesis of (2S,12′R)-2-(12′-aminotridecyl)pyrrolidine [(S,R)-8], a defense alkaloid of the Mexican bean beetle Epilachna varivestis starting from (R)-proline is described. The second stereogenic center is generated by nucleophilic 1,2-addition of methyllithium to an aldehyde-SAMP-hydrazone, followed by reductive N-N bond cleavage. The product is obtained in good yield and high enantiomeric and diastereomeric purity." @default.
- W2952746250 created "2019-06-27" @default.
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- W2952746250 date "2000-01-01" @default.
- W2952746250 modified "2023-09-24" @default.
- W2952746250 title "Efficient Synthesis of (2S,12′R)-2-(12′-Aminotridecyl)pyrrolidine: A Defense Alkaloid of the Mexican Bean Beetle" @default.
- W2952746250 doi "https://doi.org/10.1055/s-2000-6379" @default.
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