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• W2952750329 endingPage "4465" @default.
• W2952750329 startingPage "4459" @default.
• W2952750329 abstract "An ortho-alkenylation reaction of an aromatic aldimine with an internal alkyne is efficiently promoted by a cobalt catalyst generated from CoBr2, triarylphosphine, and iPrMgBr. The reaction takes place under mild room-temperature conditions to afford, upon acidic hydrolysis, a variety of ortho-alkenylated aromatic aldehydes in moderate to excellent yields. The neighboring formyl and alkenyl groups in the product can be utilized as synthetic handles for the facile construction of indene and naphthalene carbocycles." @default.
• W2952750329 created "2019-06-27" @default.
• W2952750329 creator A5024512544 @default.
• W2952750329 creator A5073328436 @default.
• W2952750329 date "2013-06-01" @default.
• W2952750329 modified "2023-10-07" @default.
• W2952750329 title "Cobalt-catalyzed ortho-alkenylation of aromatic aldimines via chelation-assisted C–H bond activation" @default.
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• W2952750329 doi "https://doi.org/10.1016/j.tet.2013.02.092" @default.
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