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- W2952762395 abstract "It is shown that 1,1-dimethyl-1,2,3,4-tetrahydroquinolinium ions undergo, under direct irradiation through quartz in CH3OH and independent of the nature of the counterion (I−, BF), a reductive cleavage of the N(1)–C(8a) bond (photo-Emde degradation). The corresponding N,N-dimethyl-3-phenylpropylamines are formed in high yields and without contamination by Hofmann degradation products of the tetrahydroquinolinium salts. Me groups at C(2) as well as substituents at C(6) (CH3, Cl, CH3O) favour the photo-Emde degradation. The aromatic Cl-substituent is reductively split off in the course of the photoreaction." @default.
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- W2952762395 date "1986-02-11" @default.
- W2952762395 modified "2023-10-17" @default.
- W2952762395 title "ChemInform Abstract: Photo-Emde Degradation of 1,2,3,4-Tetrahydroquinolinium Salts." @default.
- W2952762395 cites W2139849922 @default.
- W2952762395 doi "https://doi.org/10.1002/chin.198606074" @default.
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