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- W2952765716 abstract "The reaction of N-enoyloxazolidinones with diphenylsulfonium isoproylide in the presence of Lewis acids is explored. The diastereoselectivity of the reaction of N-enoyloxazolidinones 1a and 1b with diphenylsulfonium isopropylide could be mediated by the addition of some Lewis acids. The reaction of N-enoyloxazolidinone 4 with diphenylsulfonium isoproylide was also explored with chiral Lewis acids. When this reaction was run with bis(oxazoline) ligand 6 and a number of Lewis acids, product was obtained in as high as 95% ee. A loss of stereoselectivity was observed with less than stoichiometric amounts of Lewis acid." @default.
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- W2952765716 date "2000-11-01" @default.
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- W2952765716 title "Lewis acid mediated diastereoselective and enantioselective cyclopropanation of Michael acceptors with sulfur ylides" @default.
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- W2952765716 doi "https://doi.org/10.1016/s0040-4039(00)01534-3" @default.
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