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- W2952771729 abstract "The combined use of the Sharpless asymmetric epoxidation, a number of stereospecific chemical transformations, and the 3,5-hexadienoic acid benzannulation protocol allowed us to devise a new, divergent, and stereoselective approach to terpenes with a chiral tertiary hydroxyl group at the ortho-position of a phenol functional group. Accordingly, the natural occurring enantiomeric forms of the bisabolane sesquiterpenes (+)-curcutetraol, (+)-sydonol, (+)-sydonic acid, and (+)-7-O-methylsydonic acid were synthesized with high enantiomeric purity starting from geraniol. The latter two acids were prepared in enantioenriched form for the first time." @default.
- W2952771729 created "2019-06-27" @default.
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- W2952771729 date "2013-09-01" @default.
- W2952771729 modified "2023-09-25" @default.
- W2952771729 title "A divergent and stereoselective approach to phenolic 1,7-dihydroxy-bisabolane sesquiterpenes: asymmetric total synthesis of (+)-curcutetraol, (+)-sydonol, (+)-sydonic acid, and (+)-7-O-methylsydonic acid" @default.
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- W2952771729 doi "https://doi.org/10.1016/j.tetasy.2013.07.011" @default.
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