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- W2952783137 abstract "Reaction of [13C]methylmagnesium iodide (99 atom% 13C) with cyanohydrin O-trimethylsilyl ether 1, followed by acidic hydrolysis, led to the formation of a methyl ketone derivative 2a that was only partially labelled (60 ± 5 atom% 13C); this loss of labelling occurred through a methyl exchange reaction on silicon as shown by the presence on intermediate 2b of [13C]methyl groups on silicon (30 atom% 13C)." @default.
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- W2952783137 date "2010-06-15" @default.
- W2952783137 modified "2023-10-07" @default.
- W2952783137 title "ChemInform Abstract: Methyl Exchange on Silicon During the Addition of Methylmagnesium Iodide to a Cyanohydrin O-Silyl Ether." @default.
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- W2952783137 doi "https://doi.org/10.1002/chin.199926069" @default.
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