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- W2952783751 abstract "This paper reports on the single-phase region of cobalt Chevrel-phase compound (Co{sub y}Mo{sub 6}S{sub 8{minus}z}:CoCP) determined by x-ray diffraction analysis. The nonstoichiometric range of CoCP was very narrow and the only CoCP with y = 1.6,8 {minus} z = 7.7 could be prepared as a single phase. The CoCP was evaluated as a cathode for lithium secondary batteries. 1M CiClO{sub 4} in PC was used as an electrolyte. The discharge properties and discharge-charge cycling properties were measured galvanostatically under constant current densities from 0.1 to 2.0 mA/cm{sup 2}. The cell exhibited good discharge performance; for example when the cell was discharged under a cd = 0.1 mA/cm{sup 2}, 4.8 Li/Co{sub 1.6}Mo{sub 6}S{sub 7.7} were incorporated before the cell voltage fell down to 1.0 V (energy density: 277 Wh/kg). Also a rechargeability of more than 200 cycles was observed at cd = 0.5 mA/cm{sup 2}. The curve of OCV with varying Li content in the CoCP was very flat and near 2.1 V. The x-ray analysis of lithium incorporated cobalt Chevrel phase, Li{sub x}CoCP, was two sets of hexagonal lattice parameters showing the existence of two types of Chevrel phases (having different lattice parameters) coexisting in a wide range of 0more » {lt} x {lt} 4.5.« less" @default.
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- W2952783751 date "2010-08-23" @default.
- W2952783751 modified "2023-09-25" @default.
- W2952783751 title "ChemInform Abstract: A Rechargeable Lithium Battery Employing Cobalt Chevrel-Phase Compound as the Cathode." @default.
- W2952783751 cites W2120530589 @default.
- W2952783751 doi "https://doi.org/10.1002/chin.199126010" @default.
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