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- W2952786071 abstract "Abstract Nafion-H and Nafion SAC-13 are efficient solid Bronsted acid catalysts for the preparation of trifluoromethyl ketimines from benzylamines and trifluoromethylated ketones in high yields. A finely tuned benzylimine–benzaldimine rearrangement by facile 1,3-hydrogen shift has been achieved for the formation of fluorinated benzaldimines in high yields by careful optimization of reaction conditions including attempts under microwave conditions and a flow system. These α-trifluoromethylated benzaldimines are efficient precursors for pharmaceutically important α-trifluoromethylated benzylamines, accessed through their direct acid hydrolysis." @default.
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- W2952786071 date "2012-02-01" @default.
- W2952786071 modified "2023-09-22" @default.
- W2952786071 title "Thermocontrolled benzylimine–benzaldimine rearrangement over Nafion-H catalysts for efficient entry into α-trifluoromethylbenzylamines" @default.
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- W2952786071 doi "https://doi.org/10.1016/j.tetlet.2011.11.088" @default.
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