Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952791608> ?p ?o ?g. }
- W2952791608 endingPage "166" @default.
- W2952791608 startingPage "121" @default.
- W2952791608 abstract "This chapter discusses the remarkable progress in the chemistry of heavy ketones leading to the systematic comparison of their structures and properties that are capable of existence as stable species if their highly reactive M=X bond is adequately protected toward dimerization. Kinetic stabilization is superior to thermodynamic stabilization to elucidate the intrinsic nature of heavy ketones. A more general account of the whole chemistry of stable double bonds between heavier Group 14 and Group 16 elements is reviewed. The structural features of their M=X bonds (M = Si, Ge, Sn; X = chalcogen atom), such as trigonal planar geometry and bond shortening compared to the corresponding M–X single bonds are similar to those of ketones, heavy ketones have much higher reactivity because of their weak π bonds. The systematic study on heavy ketones containing silicon through lead using steric protection with the Tbt group reveals that a heavy ketone containing lead, R2Pb═X, is unique in that it is less stable than its isomeric lumbylene RPb–XR." @default.
- W2952791608 created "2019-06-27" @default.
- W2952791608 creator A5055614215 @default.
- W2952791608 creator A5089902442 @default.
- W2952791608 date "2001-01-01" @default.
- W2952791608 modified "2023-09-30" @default.
- W2952791608 title "Recent advances in the chemistry of group 14-group 16 double bond compounds" @default.
- W2952791608 cites W1483189535 @default.
- W2952791608 cites W1510200084 @default.
- W2952791608 cites W1964596846 @default.
- W2952791608 cites W1966171346 @default.
- W2952791608 cites W1966743317 @default.
- W2952791608 cites W1970194271 @default.
- W2952791608 cites W1970522713 @default.
- W2952791608 cites W1971388833 @default.
- W2952791608 cites W1971883986 @default.
- W2952791608 cites W1972357068 @default.
- W2952791608 cites W1972730444 @default.
- W2952791608 cites W1975975622 @default.
- W2952791608 cites W1977019893 @default.
- W2952791608 cites W1979848497 @default.
- W2952791608 cites W1980132806 @default.
- W2952791608 cites W1980494069 @default.
- W2952791608 cites W1985764311 @default.
- W2952791608 cites W1986697169 @default.
- W2952791608 cites W1987998137 @default.
- W2952791608 cites W1989429176 @default.
- W2952791608 cites W1990896636 @default.
- W2952791608 cites W1991311785 @default.
- W2952791608 cites W1995491976 @default.
- W2952791608 cites W2012350801 @default.
- W2952791608 cites W2012399467 @default.
- W2952791608 cites W2017813412 @default.
- W2952791608 cites W2019854908 @default.
- W2952791608 cites W2021090826 @default.
- W2952791608 cites W2022128380 @default.
- W2952791608 cites W2028231193 @default.
- W2952791608 cites W2028937569 @default.
- W2952791608 cites W2028970781 @default.
- W2952791608 cites W2029225180 @default.
- W2952791608 cites W2031318608 @default.
- W2952791608 cites W2031378482 @default.
- W2952791608 cites W2034957768 @default.
- W2952791608 cites W2035364036 @default.
- W2952791608 cites W2037314521 @default.
- W2952791608 cites W2039309493 @default.
- W2952791608 cites W2042118444 @default.
- W2952791608 cites W2042125006 @default.
- W2952791608 cites W2044807989 @default.
- W2952791608 cites W2046035292 @default.
- W2952791608 cites W2048871833 @default.
- W2952791608 cites W2049579282 @default.
- W2952791608 cites W2050494253 @default.
- W2952791608 cites W2050666868 @default.
- W2952791608 cites W2054297283 @default.
- W2952791608 cites W2056577756 @default.
- W2952791608 cites W2058202055 @default.
- W2952791608 cites W2058432457 @default.
- W2952791608 cites W2060178343 @default.
- W2952791608 cites W2060571703 @default.
- W2952791608 cites W2061674615 @default.
- W2952791608 cites W2062114283 @default.
- W2952791608 cites W2063244547 @default.
- W2952791608 cites W2065509376 @default.
- W2952791608 cites W2069284456 @default.
- W2952791608 cites W2071032959 @default.
- W2952791608 cites W2071396023 @default.
- W2952791608 cites W2073875504 @default.
- W2952791608 cites W2078798096 @default.
- W2952791608 cites W2082471687 @default.
- W2952791608 cites W2091906028 @default.
- W2952791608 cites W2092573935 @default.
- W2952791608 cites W2101749480 @default.
- W2952791608 cites W2116487749 @default.
- W2952791608 cites W2119657824 @default.
- W2952791608 cites W2144032406 @default.
- W2952791608 cites W2149490427 @default.
- W2952791608 cites W2159802027 @default.
- W2952791608 cites W2159968793 @default.
- W2952791608 cites W2165473284 @default.
- W2952791608 cites W2170908017 @default.
- W2952791608 cites W2313561045 @default.
- W2952791608 cites W2317020368 @default.
- W2952791608 cites W2334235465 @default.
- W2952791608 cites W2336285380 @default.
- W2952791608 cites W2949354781 @default.
- W2952791608 cites W2949364562 @default.
- W2952791608 cites W2949406252 @default.
- W2952791608 cites W2949635963 @default.
- W2952791608 cites W2949866219 @default.
- W2952791608 cites W2949972383 @default.
- W2952791608 cites W2950969035 @default.
- W2952791608 cites W2951383574 @default.
- W2952791608 cites W2951506868 @default.
- W2952791608 cites W2951965072 @default.
- W2952791608 cites W2952080366 @default.
- W2952791608 cites W2952407437 @default.
- W2952791608 cites W2952417288 @default.