Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952803557> ?p ?o ?g. }
Showing items 1 to 63 of
63
with 100 items per page.
- W2952803557 abstract "Photoinduced biomimetic cascade cyclizations of suitably functionalized terpenoid arylpolyalkenes via radical cationic intermediates represent a powerful route to polycyclic compounds in a single operational step. In all cases examined, the radical cation, created selectively and exclusively at the ψ-polyalkene position, is trapped in anti-Markovnikov fashion by water, liberating a free radical site, which ultimately initiates cascade-style bond formation to afford the all-chair polycyclic conformation containing one aromatic moiety. The products, some of which are podocarpic-type structures 17−19, are beneficially 3β-hydroxylated. Mechanistically, the reaction is probably initiated by a radical cation trapped by water prior to the cyclization event, which is driven by a pure radical-type process. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
- W2952803557 created "2019-06-27" @default.
- W2952803557 creator A5018060320 @default.
- W2952803557 creator A5040084745 @default.
- W2952803557 creator A5052797219 @default.
- W2952803557 date "2004-08-10" @default.
- W2952803557 modified "2023-09-23" @default.
- W2952803557 title "Straightforward Synthesis of Aromatic Polycyclic Terpenoids Through Biomimetic Cascade Cyclizations Triggered by Photochemical Electron Transfer." @default.
- W2952803557 cites W2076311011 @default.
- W2952803557 doi "https://doi.org/10.1002/chin.200432197" @default.
- W2952803557 hasPublicationYear "2004" @default.
- W2952803557 type Work @default.
- W2952803557 sameAs 2952803557 @default.
- W2952803557 citedByCount "0" @default.
- W2952803557 crossrefType "journal-article" @default.
- W2952803557 hasAuthorship W2952803557A5018060320 @default.
- W2952803557 hasAuthorship W2952803557A5040084745 @default.
- W2952803557 hasAuthorship W2952803557A5052797219 @default.
- W2952803557 hasConcept C123669783 @default.
- W2952803557 hasConcept C161790260 @default.
- W2952803557 hasConcept C178790620 @default.
- W2952803557 hasConcept C183882617 @default.
- W2952803557 hasConcept C185592680 @default.
- W2952803557 hasConcept C20327893 @default.
- W2952803557 hasConcept C2776568683 @default.
- W2952803557 hasConcept C2781018080 @default.
- W2952803557 hasConcept C34146451 @default.
- W2952803557 hasConcept C43617362 @default.
- W2952803557 hasConcept C59759590 @default.
- W2952803557 hasConcept C71240020 @default.
- W2952803557 hasConcept C75473681 @default.
- W2952803557 hasConcept C98939719 @default.
- W2952803557 hasConceptScore W2952803557C123669783 @default.
- W2952803557 hasConceptScore W2952803557C161790260 @default.
- W2952803557 hasConceptScore W2952803557C178790620 @default.
- W2952803557 hasConceptScore W2952803557C183882617 @default.
- W2952803557 hasConceptScore W2952803557C185592680 @default.
- W2952803557 hasConceptScore W2952803557C20327893 @default.
- W2952803557 hasConceptScore W2952803557C2776568683 @default.
- W2952803557 hasConceptScore W2952803557C2781018080 @default.
- W2952803557 hasConceptScore W2952803557C34146451 @default.
- W2952803557 hasConceptScore W2952803557C43617362 @default.
- W2952803557 hasConceptScore W2952803557C59759590 @default.
- W2952803557 hasConceptScore W2952803557C71240020 @default.
- W2952803557 hasConceptScore W2952803557C75473681 @default.
- W2952803557 hasConceptScore W2952803557C98939719 @default.
- W2952803557 hasLocation W29528035571 @default.
- W2952803557 hasOpenAccess W2952803557 @default.
- W2952803557 hasPrimaryLocation W29528035571 @default.
- W2952803557 hasRelatedWork W2010056265 @default.
- W2952803557 hasRelatedWork W2119717738 @default.
- W2952803557 hasRelatedWork W2342660471 @default.
- W2952803557 hasRelatedWork W2344058875 @default.
- W2952803557 hasRelatedWork W2346698353 @default.
- W2952803557 hasRelatedWork W2794956961 @default.
- W2952803557 hasRelatedWork W2811054971 @default.
- W2952803557 hasRelatedWork W2950422491 @default.
- W2952803557 hasRelatedWork W2952264393 @default.
- W2952803557 hasRelatedWork W3136765699 @default.
- W2952803557 isParatext "false" @default.
- W2952803557 isRetracted "false" @default.
- W2952803557 magId "2952803557" @default.
- W2952803557 workType "article" @default.