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- W2952803866 abstract "Dynamics and mechanisms of infrared multiphoton dissociation of CBrF2CHClF, CBrF2CHBrF, and CBrClFCBrF2 have been studied using a photofragmentation translational spectroscopy. All molecules dissociated through C–Br bond rupture reactions. At high laser fluence, the halogenated ethyl radicals produced by the primary dissociation reactions dissociated through carbon–halogen bond ruptures. Center-of-mass product translational energy distributions for the C–Br and C–Cl bond ruptures of all halogenated ethanes and ethyl radicals studied are essentially consistent with those calculated by Rice–Ramsperger–Kassel–Marcus (RRKM) theory. This indicates that there exists essentially no exit channel barrier on the potential energy surface for the C–Br or C–Cl bond rupture of the halogenated ethanes and ethyl radicals." @default.
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- W2952803866 date "1994-12-15" @default.
- W2952803866 modified "2023-09-27" @default.
- W2952803866 title "Infrared multiphoton dissociation of CBrF2CHClF, CBrF2CHBrF, and CBrClFCBrF2 in a molecular beam" @default.
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- W2952803866 doi "https://doi.org/10.1063/1.468442" @default.
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