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- W2952804053 abstract "A new and general method for preparing Fischer-type alkoxycarbene complexes 1 is reported. This method involves the alkylation of acylate complexes 7 with alkyldiphenylsulfonium salts 10 with a variety of functionalized alkyl groups. The alkylation of tetramethylammonium pentacarbonyl(1-oxyalkylidene)chromate(0) 7a-c, tetramethylammonium pentacarbonyl(1-oxymethylidene)molybdate(0) 7d, and pentacarbonyl(1-oxymethylidene)tungstate(0) 7e with alkyldiphenylsulfonium salts 10 proceeded smoothly under mild conditions to give the corresponding alkoxycarbene complexes 12-39 in good to high yields. Competitive alkylation of 7a with methyl-11 and isopropyldiphenylsulfonium tetrafluoroborate 40 shows a higher reactivity of the isopropyl group, suggesting the participation of an S-O sulfurane intermediate 41." @default.
- W2952804053 created "2019-06-27" @default.
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- W2952804053 date "2000-11-28" @default.
- W2952804053 modified "2023-09-23" @default.
- W2952804053 title "ChemInform Abstract: Synthesis of Fischer-Type (Alkoxy)carbene Complexes Using Diphenylsulfonium Salts with Functionalized Alkyl Groups." @default.
- W2952804053 cites W1981780291 @default.
- W2952804053 doi "https://doi.org/10.1002/chin.200048084" @default.
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