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- W2952804612 abstract "The cation distribution in a series of MgxMn1.1−xSn0.1Fe1.8O4 spinel ferrites has been studied by means of X-ray powder diffraction and 57Fe, 119Sn Mossbauer spectroscopy. All of these ferrites showed broad 119Sn Mossbauer spectra due to the hyperfine magnetic field from the ferrimagnetically ordered cations at the A and B sites. With increasing x the distribution of the hyperfine field at the Sn atom became broader and the hyperfine field decreased abruptly above x=0.825. This observation indicates that diamagnetic Mg2+ ions are excluded from the A site below x=0.55, but occupy the A site as well as the B site only above x=0.825. This result is consistent with the Rietveld analyses of the X-ray powder diffraction data. The 119Sn Mossbauer spectroscopy is shown to be a useful technique for studying the cation distribution of ternary spinels in which the site preference of cations can not be empirically predicted." @default.
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- W2952804612 date "1990-11-01" @default.
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- W2952804612 title "Cation Distribution in a Series of Mixed Ferrites Mg<i><sub>x</sub></i>Mn<sub>1.1−<i>x</i></sub>Sn<sub>0.1</sub>Fe<sub>1.8</sub>O<sub>4</sub>by Means of Powder X-Ray Diffraction and<sup>57</sup>Fe,<sup>119</sup>Sn Mössbauer Spectroscopy" @default.
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- W2952804612 doi "https://doi.org/10.1246/bcsj.63.3193" @default.
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