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- W2952805989 abstract "Phenyl chloroformate (1) reacts with the allylsilanes 2a–h in the presence of aluminium chloride to give the β,γ-unsaturated phenyl esters 3a–h in 50–90% yield. While these reactions proceed in the usual manner with allylic inversion, (1,1-dimethylallyl)trimethylsilane (2i) reacts with allyl retention to yield the 2,2-dimethyl-3-butenoate 3i. Attempts to use 1 for the phenoxycarbonylation of arenes were not successful." @default.
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- W2952805989 date "1995-09-01" @default.
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- W2952805989 title "Synthesis of β,γ-unsaturated phenyl esters by aluminium chloride initiated reactions of allylsilanes with aryl chloroformates" @default.
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- W2952805989 doi "https://doi.org/10.1002/jlac.1995199509220" @default.
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