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- W2952806006 abstract "Treatment of bis(o-nitrophenyl)disulfides 1 with SmI2 led to simultaneous reduction of nitro groups and reductive cleavage of S–S bonds as well as the formation of the active intermediates 2. The intermediates 2 reacted smoothly with aldehydes or ketones, acid chlorides or anhydrides, α-bromoketones, and α,β-unsaturated ketones at room temperature to afford the desired benzothiazolines 3, benzothiazoles 4, 2H-1,4-benzothiazines 5, and 2,3-dihydro-1,5-benzothiazepines 6, respectively, in moderate to high yields under mild and neutral conditions. © 2001 John Wiley & Sons, Inc. Heteroatom Chem 12:156–160, 2001" @default.
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- W2952806006 date "2001-01-01" @default.
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- W2952806006 title "Conversion of bis(o-nitrophenyl)disulfides to heterocycles containing sulfur and nitrogen by the action of samarium diiodide" @default.
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- W2952806006 doi "https://doi.org/10.1002/hc.1025" @default.
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