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- W2952806844 abstract "α-Al2O3-seeded, boehmite-derived γ-Al2O3 was transformed in the presence of V2O5, resulting in a 205°C decrease in the α-Al2O3 transformation temperature and a 74% reduction in the apparent activation energy for the γ- to α-Al2O3 transformation at temperatures greater than 850°C. These changes are attributed to the lowered energy barrier for nucleation by seeding and the lowered activation energy for material transport through the liquid relative to the unseeded, solid-state transformation. Growth of the transforming alumina yielded fine-grained α-Al2O3 particles which exhibited a highly faceted morphology. It is proposed that the combined control of both nucleation and growth during liquid-phase-assisted transformation provides a potentially powerful technique for tailoring powder characteristics in many material systems which undergo nucleation and growth processes." @default.
- W2952806844 created "2019-06-27" @default.
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- W2952806844 date "1988-07-26" @default.
- W2952806844 modified "2023-09-26" @default.
- W2952806844 title "ChemInform Abstract: Liquid-Phase-Assisted Transformation of Seeded γ-Alumina." @default.
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- W2952806844 doi "https://doi.org/10.1002/chin.198830342" @default.
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