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• W2952807432 abstract "[rection: see text] The first regioselective alpha-deprotonation and functionalization of electron-deficient allenamines are described here. The acidities of alpha- and gamma-allenic protons of these allenamides are readily differentiated using strong bases, thereby allowing regioselective substitutions at either the alpha- or gamma-allenic position. A specific synthetic application of the novel alpha-substituted allenamides in intramolecular Pauson-Khand-type cycloadditions is also described here." @default.
• W2952807432 created "2019-06-27" @default.
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• W2952807432 date "2000-08-17" @default.
• W2952807432 modified "2023-10-15" @default.
• W2952807432 title "The First Regioselective α-Deprotonation and Functionalization of Allenamides. An Application in Intramolecular Pauson−Khand-Type Cycloadditions" @default.
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• W2952807432 doi "https://doi.org/10.1021/ol000181+" @default.
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