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- W2952808439 abstract "The sequential insertion of carbon monoxide and imines has been achieved at ambient temperatures with cationic nickel complexes, yielding the nickel-chelated amides (bipy)Ni[η2-C(H)TolN(R)COCH3]+X- (bipy = 2,2‘-bipyridyl; Tol = p-tolyl; R = alkyl, aryl; X = OTf, PF6, SbF6, B(3,5-C6H3(CF3)2)4). The addition of KCN/methanol to these products of CO/imine insertion leads to cleavage of the amide ligand, providing a facile method to achieve the overall hydroacylation of imines under mild conditions." @default.
- W2952808439 created "2019-06-27" @default.
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- W2952808439 date "2000-10-12" @default.
- W2952808439 modified "2023-09-24" @default.
- W2952808439 title "Sequential Insertion of Carbon Monoxide and Imines into Nickel−Methyl Bonds: A New Route to Imine Hydroacylation" @default.
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- W2952808439 doi "https://doi.org/10.1021/om000685b" @default.
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