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- W2952808503 abstract "The synthesis and reactivity of transition-metal complexes containing heteropentadienyl ligands (i.e., pentadienyl analogues in which one terminal carbon has been replaced by a heteroatom) are reviewed. Specifically, four compound classes are covered: oxapentadienyl−metal, azapentadienyl−metal, thiapentadienyl−metal, and phosphapentadienyl−metal complexes. Within each of these classes, contributions are presented in approximate chronological order. Particular attention is given to the development of rational synthetic methodologies. A second focus is the unique reactivity of these compounds, much of which stems from the ability of the heteropentadienyl ligands to adopt a variety of bonding modes and shuttle easily between them." @default.
- W2952808503 created "2019-06-27" @default.
- W2952808503 creator A5049759755 @default.
- W2952808503 date "2005-09-24" @default.
- W2952808503 modified "2023-10-16" @default.
- W2952808503 title "Synthesis and Reactivity of Heteropentadienyl−Transition-Metal Complexes" @default.
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- W2952808503 doi "https://doi.org/10.1021/om058044+" @default.
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