Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952809906> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W2952809906 abstract "Abstract A visual determination of the phase diagram of the MgCl2-AlCl3 system reveals the formation of two intermediate compounds. One of these compounds is MgAl2Cl8 crystallizing with a monoclinic unit cell, space group I2/c, with dimensions a = 12.873(1)A, b = 7.8959(7)A, c = 11.617(1)A, β = 92.348(8)° and z = 4. The two crystal modifications of anhydrous magnesium chloride and the lattice parameters of aluminium chloride have been reexamined. Lattice energies for α- and β-MgCl2 have been measured, respectively, as 661(1) and 646(4) kcal mol−1. The liquidus curve on the acidic side has been used to estimate the activity of aluminium chloride. Fourier-transform IR spectra of melts with compositions ranging from 0 to 30 mol% MgCl2 have been interpreted in terms of Al2Cl6, strongly perturbed Al2Cl7− and AlCl4− entities. In particular, the tetrachloroaluminate ion acts as both a tri- and a bidentate ligand towards Mg2+. Neutral species, e.g. Mg(AlCl4)2 and Mg(Al2Cl6)(AlCl4)Cl, dominate in the melt. Ab initio molecular-orbital calculations have been performed to obtain a better understanding of the Mg2+ —d AlCl4− interaction." @default.
- W2952809906 created "2019-06-27" @default.
- W2952809906 creator A5011155090 @default.
- W2952809906 creator A5062603587 @default.
- W2952809906 creator A5065099661 @default.
- W2952809906 creator A5077109664 @default.
- W2952809906 date "1987-07-28" @default.
- W2952809906 modified "2023-09-23" @default.
- W2952809906 title "ChemInform Abstract: Structure and Stability of Solid and Molten Complexes in the MgCl2-AlCl3 System." @default.
- W2952809906 cites W2014912291 @default.
- W2952809906 doi "https://doi.org/10.1002/chin.198730017" @default.
- W2952809906 hasPublicationYear "1987" @default.
- W2952809906 type Work @default.
- W2952809906 sameAs 2952809906 @default.
- W2952809906 citedByCount "0" @default.
- W2952809906 crossrefType "journal-article" @default.
- W2952809906 hasAuthorship W2952809906A5011155090 @default.
- W2952809906 hasAuthorship W2952809906A5062603587 @default.
- W2952809906 hasAuthorship W2952809906A5065099661 @default.
- W2952809906 hasAuthorship W2952809906A5077109664 @default.
- W2952809906 hasConcept C115624301 @default.
- W2952809906 hasConcept C145148216 @default.
- W2952809906 hasConcept C147789679 @default.
- W2952809906 hasConcept C178516000 @default.
- W2952809906 hasConcept C178790620 @default.
- W2952809906 hasConcept C179104552 @default.
- W2952809906 hasConcept C185592680 @default.
- W2952809906 hasConcept C187714232 @default.
- W2952809906 hasConcept C2778695967 @default.
- W2952809906 hasConcept C44280652 @default.
- W2952809906 hasConcept C543218039 @default.
- W2952809906 hasConcept C61276311 @default.
- W2952809906 hasConcept C8010536 @default.
- W2952809906 hasConcept C85906118 @default.
- W2952809906 hasConceptScore W2952809906C115624301 @default.
- W2952809906 hasConceptScore W2952809906C145148216 @default.
- W2952809906 hasConceptScore W2952809906C147789679 @default.
- W2952809906 hasConceptScore W2952809906C178516000 @default.
- W2952809906 hasConceptScore W2952809906C178790620 @default.
- W2952809906 hasConceptScore W2952809906C179104552 @default.
- W2952809906 hasConceptScore W2952809906C185592680 @default.
- W2952809906 hasConceptScore W2952809906C187714232 @default.
- W2952809906 hasConceptScore W2952809906C2778695967 @default.
- W2952809906 hasConceptScore W2952809906C44280652 @default.
- W2952809906 hasConceptScore W2952809906C543218039 @default.
- W2952809906 hasConceptScore W2952809906C61276311 @default.
- W2952809906 hasConceptScore W2952809906C8010536 @default.
- W2952809906 hasConceptScore W2952809906C85906118 @default.
- W2952809906 hasLocation W29528099061 @default.
- W2952809906 hasOpenAccess W2952809906 @default.
- W2952809906 hasPrimaryLocation W29528099061 @default.
- W2952809906 hasRelatedWork W1500670842 @default.
- W2952809906 hasRelatedWork W1978304581 @default.
- W2952809906 hasRelatedWork W2000561243 @default.
- W2952809906 hasRelatedWork W2001986332 @default.
- W2952809906 hasRelatedWork W2036393230 @default.
- W2952809906 hasRelatedWork W2037508933 @default.
- W2952809906 hasRelatedWork W2049100144 @default.
- W2952809906 hasRelatedWork W2053876872 @default.
- W2952809906 hasRelatedWork W2059744075 @default.
- W2952809906 hasRelatedWork W2070251338 @default.
- W2952809906 hasRelatedWork W2087418393 @default.
- W2952809906 hasRelatedWork W2093994573 @default.
- W2952809906 hasRelatedWork W2096817074 @default.
- W2952809906 hasRelatedWork W2124056076 @default.
- W2952809906 hasRelatedWork W2240614779 @default.
- W2952809906 hasRelatedWork W2394858556 @default.
- W2952809906 hasRelatedWork W2912483321 @default.
- W2952809906 hasRelatedWork W2949303558 @default.
- W2952809906 hasRelatedWork W2951101736 @default.
- W2952809906 hasRelatedWork W2953251030 @default.
- W2952809906 isParatext "false" @default.
- W2952809906 isRetracted "false" @default.
- W2952809906 magId "2952809906" @default.
- W2952809906 workType "article" @default.